Drastic Dependence of the pH Sensitivity of Fe2O3-Bi2O3-B2O3 Hydrophobic Glasses with Composition

نویسندگان

  • Tadanori Hashimoto
  • Fumiya Murayama
  • Masashi Nakao
  • Hiroyuki Nasu
  • Atsushi Ishihara
  • Yuji Nishio
چکیده

Fe2O3-Bi2O3-B2O3 (FeBiB) glasses were developed as novel pH responsive hydrophobic glasses. The influence of the glass composition on the pH sensitivity of FeBiB glasses was investigated. The pH sensitivity drastically decreased with decreasing B2O3 content. A moderate amount of Fe2O3 and a small amount of B2O3 respectively produces bulk electronic conduction and a pH response on glass surfaces. Because the remaining components of the glass can be selected freely, this discovery could prove very useful in developing novel pH glass electrodes that are self-cleaning and resist fouling.

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عنوان ژورنال:

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2015